Airborne black carbon concentrations over an urban region in western India—temporal variability, effects of meteorology, and source regions

This study characterizes over 5 years of high time resolution (5 min), airborne black carbon (BC) concentrations (July 2003 to December 2008) measured over Ahmedabad, an urban region in western India. The data were used to obtain different time averages of BC concentrations, and these averages were then used to assess the diurnal, seasonal, and annual variability of BC over the study region. Assessment of diurnal variations revealed a strong association between BC concentrations and vehicular traffic. Peaks in BC concentration were co-incident with the morning (0730 to 0830, LST) and late evening (1930 to 2030, LST) rush hour traffic. Additionally, diurnal variability in BC concentrations during major festivals (Diwali and Dushera during the months of October/November) revealed an increase in BC concentrations due to fireworks displays. Maximum half hourly BC concentrations during the festival days were as high as 79.8 μg m^?3. However, the high concentrations rapidly decayed suggesting that local meteorology during the festive season was favorable for aerosol dispersion. A multiple linear regression (MLR) model with BC as the dependent variable and meteorological parameters as independent variables was fitted. The variability in temperature, humidity, wind speed, and wind direction accounted for about 49% of the variability in measured BC concentrations. Conditional probability function (CPF) analysis was used to identify the geographical location of local source regions contributing to the effective BC measured (at 880 nm) at the receptor site. The east north-east (ENE) direction to the receptor was identified as a major source region. National highway (NH8) and two coal-fired thermal power stations (at Gandhinagar and Sabarmati) were located in the identified direction, suggesting that local traffic and power plant emissions were likely contributors to the measured BC.     

Megacities and Large Urban Agglomerations in the Coastal Zone: Interactions Between Atmosphere, Land, and Marine Ecosystems

Megacities are not only important drivers for socio-economic development but also sources of environmental challenges. Many megacities and large urban agglomerations are located in the coastal zone where land, atmosphere, and ocean meet, posing multiple environmental challenges which we consider here. The atmospheric flow around megacities is complicated by urban heat island effects and topographic flows and sea breezes and influences air pollution and human health. The outflow of polluted air over the ocean perturbs biogeochemical processes. Contaminant inputs can damage downstream coastal zone ecosystem function and resources including fisheries, induce harmful algal blooms and feedback to the atmosphere via marine emissions. The scale of influence of megacities in the coastal zone is hundreds to thousands of kilometers in the atmosphere and tens to hundreds of kilometers in the ocean. We list research needs to further our understanding of coastal megacities with the ultimate aim to improve their environmental management.     

Soil carbon storage in silvopasture and related land-use systems in the brazilian cerrado

Silvopastoral management of fast-growing tree plantations is becoming popular in the Brazilian Cerrado (savanna). To understand the influence of such systems on soil carbon (C) storage, we studied C content in three aggregate size classes in six land-use systems (LUS) on Oxisols in Minas Gerais, Brazil. The systems were a native forest, a treeless pasture, 24- and 4-yr-old eucalyptus ( sp.) plantations, and 15- and 4-yr-old silvopastures of fodder grass plus animals under eucalyptus. From each system, replicated soil samples were collected from four depths (0-10, 10-20, 20-50, and 50-100 cm), fractionated into 2000- to 250-, 250- to 53-, and <53-μm size classes representing macroaggregates, microaggregates, and silt + clay, respectively, and their C contents determined. Macroaggregate was the predominant size fraction under all LUS, especially in the surface soil layers of tree-based systems. In general, C concentrations (g kg soil) in the different aggregate size fractions did not vary within the same depth. The soil organic carbon (SOC) stock (Mg C ha) to 1-m depth was highest under pasture compared with other LUS owing to its higher soil bulk density. The soils under all LUS had higher C stock compared with other reported values for managed tropical ecosystems: down to 1 m, total SOC stock values ranged from 461 Mg ha under pasture to 393 Mg ha under old eucalyptus. Considering the possibility for formation and retention of microaggregates within macroggregates in low management-intensive systems such as silvopasture, the macroaggregate dynamics in the soil seem to be a good indicator of its C storage potential.     

Soil carbon storage in silvopastoral systems and a treeless pasture in northwestern Spain

Soil particle size and land management practices are known to have considerable influence on carbon (C) storage in soils, but such information is lacking for silvopastoral systems in Spain. This study quantified the amounts of soil C stored at various depths to 100 cm under silvopastoral plots of radiata pine ( D. Don) and birch ( Roth) in comparison to treeless pasture in Galicia, Spain. Soils were fractionated into three size classes (<53, 53-250, and 250-2000 μm), and C stored in them and in the whole (nonfractionated) soil was determined. Overall, the C stock to 1 m ranged from 80.9 to 176.9 Mg ha in these soils. Up to 1 m depth, 78.82% of C was found in the 0- to 25-cm soil depth, with 12.9, 4.92, and 3.36% in the 25- to 50-, 50- to 75-, and 75- to 100-cm depths, respectively. Soils under birch at 0 to 25 cm stored more C in the 250- to 2000-μm size class as compared with those under radiata pine; at that depth, pasture had more C than pine silvopasture in the smaller soil fractions (<53 and 53-250 μm). In the 75- to 100-cm depth, there was significantly more storage of C in the 250- to 2000-μm fraction in both silvopastures as compared with the pasture. The higher storage of soil C in larger fraction size in lower soil depths of silvopasture suggests that planting of trees into traditional agricultural landscapes will promote longer-term storage of C in the soil.     

Agroforestry systems and environmental quality: introduction

Investments in agroforestry research during the past three decades-albeit modest-have yielded significant gains in understanding the role of trees on farmlands, and the ecological and economic advantages of integrated farming systems. While early research focused mostly on farm or local levels, broader-level ecosystem services of agroforestry systems (AFS) have raised high expectations in recent years. The nine papers included in this special collection deal with three of such environmental benefits of AFS: water-quality enhancement, carbon sequestration, and soil improvement. These benefits are based on the perceived ability of (i) vegetative buffer strips (VBS) to reduce surface transport of agrochemical pollutants, (ii) large volumes of aboveground and belowground biomass of trees to store high amounts of C deeper in the soil profile, and (iii) trees to enhance soil productivity through biological nitrogen fixation, efficient nutrient cycling, and deep capture of nutrients. The papers included have, in general, substantiated these premises and provided new insights. For example, the riparian VBS are reported to increase the reservoir life, in addition to reducing transport of agrochemicals; the variations in C storage in different soil-fraction sizes suggest that microaggregate (250-53 μm) dynamics in the soil could be a good indicator of its C-storage potential; and the use of vector analysis technique is recommended in AFS to avoid consequences of inaccurate and overuse of fertilizers. The papers also identified significant knowledge gaps in these areas. A common theme across all three environmental quality issues covered is that more and varied research datasets across a broad spectrum of conditions need to be generated and integrated with powerful statistical tools to ensure wide applicability of the results. Furthermore, appropriate management practices that are acceptable to the targeted land users and agroforestry practitioners need to be designed to exploit these environmental benefits. The relative newness of research in environmental quality of AFS will pose some additional challenges as well. These include the lack of allometric equations for tree-biomass determination, absence of standardized norms on soil sampling depth, and limitations of fixed-effect models arising from issues such as pseudo-replication and repeated measures that are common in studies on preexisting field plots. Overall, this special collection is a timely effort in highlighting the promise of AFS in addressing some of the environmental quality issues, and the challenges in realizing that potential.     

Prenatal diagnosis of mucopolysaccharidosis type VII facilitating treatment in neonatal period

Duo exome testing was performed on a fetus conceived via in vitro fertilization with an egg donor. The fetus presented with non-immune hydrops fetalis (NIHF) at 20 + 0 weeks gestation. Two variants were detected in the GUSB gene. Biallelic pathogenic variants cause mucopolysaccharidosis type VII (MPS-VII), which can present with NIHF prenatally. At the time of analysis and initial report, one variant was classified as likely pathogenic and the other as of uncertain clinical significance. Biochemical testing of the amniotic fluid supernatant showed elevated glycosaminoglycans and low β-glucuronidase activity consistent with the diagnosis of MPS-VII. This evidence allowed the upgrade of the pathogenicity for both variants, confirming the diagnosis of MPS-VII. The infant was born at 36 + 5 weeks and enzyme replacement therapy (ERT) using vestronidase was initiated at 20 days with planning for hematopoietic stem cell transplant ongoing. The ERT therapy has been well tolerated, with decreasing quantitative urine glycosaminoglycans. Long-term follow up is required to determine whether treatment has been successful. This case demonstrates the utility of alternative testing methods to clarify the pathogenicity of variants and the clinical utility of obtaining a diagnosis antenatally in facilitating treatment in the neonatal period, and specifically highlights MPS-VII as a treatable cause of NIHF.     

Seawater intrusion vulnerability in the coastal aquifers of southern India—an appraisal of the GALDIT model,parameters’ sensitivity,and hydrochemical indicators

An appraisal of seawater intrusion into the coastal aquifers is one of the major issues for groundwater resource management. The GALDIT model applies to the analysis of multiple parameters using systematic GIS techniques for mapping and assessment of seawater intrusion vulnerability. It demarcates the mapping of potential vulnerability that shows a higher vulnerability to seawater intrusion in various parts of the coast and the estimated vulnerability index value of 7.50 and 9.64. An area of 33.0 km² spread in the low-lying coastal area comprising estuaries, salt marshes, and saltpans shows the high vulnerability condition with an estimated vulnerability value of 6.42–7.50. An area of 73.20 km² spread over coastal and alluvial plains experiences moderate vulnerability (temporal salinity in the groundwater sources) with an estimated vulnerability index value of 5.46–6.42. Aquifers underlying coastal uplands (hard rock formations) and some parts of accretionary beaches (2.05 km²) are relatively protected fresh groundwater sources, wherein the estimated vulnerability index is 4.55–5.46. The vulnerability mapping of the GALDIT model using hydrochemical analysis of primary groundwater parameters such as TDS, Cl^?, HCO₃, and Cl^?/HCO₃ ratio is validated. Higher concentration of TDS (2637–4162 mg/l) and Cl^? (1268–2347 mg/l) is taken for the areas falling under higher vulnerability to seawater intrusion, especially in the placer mining sites and coastal areas facing erosion. Similarly, the groundwater sources of the low-lying areas including estuaries, salt marshes, saltpans, and backwater were noted to have higher values of Cl^?/HCO₃ with a rationality of 9.87–12.18. Hydrological facies shows the highest concentration of NaCl in the groundwater sources within the proximity of eroded beaches, saltwater bodies, and sand mining areas. A hydrochemical facies evolution (HFE) diagram represents the hydrochemical facies of groundwater elements that shows an intrusion of seawater into the coastal aquifers underlying the very high vulnerable zones. Higher bicarbonate concentration (233–318 mg/l) is noticed in the upland areas and some parts of dunes and accreted beaches, sandy coasts, and uplands. Vulnerability analysis reveals that those areas near saltwater bodies and eroding coasts are prone to lateral and vertical diffusion of saltwater. The geodatabase developed through such modeling studies can help in planning and developing activities for sustainable groundwater resource management in coastal areas.

     

Synergetic integration of laccase and versatile peroxidase with magnetic silica microspheres towards remediation of biorefinery wastewater

In this study, a tailor-made biocatalyst consisting of a co-immobilized lignolytic enzyme cascade on multi-functionalized magnetic silica microspheres (MSMS) was developed. Physical adsorption was the most promising strategy for the synthesis of individual immobilized laccase (IL), immobilized versatile peroxidase (IP), as well as co-immobilized laccase (Lac) and versatile peroxidase (VP) with an enzyme activity recovery of about 79, 93, 27, and 27.5%, respectively. Similarly, the biocatalytic load of 116, 183, 23.6, and 31 U/g was obtained for IL, IP, and co-immobilized Lac and VP, respectively. The co-immobilized enzyme system exhibited better pH stability than the free and individual immobilized system by retaining more than 100% residual activity at pH 7.0 after a 150-h incubation; whereas, the thermal stability and kinetics of the co-immobilized biocatalyst were not much improved. IL and IP could be recycled for 10 cycles after which they retained 31 and 44% of their initial activities. Co-immobilized Lac and VP were reused for ten consecutive cycles at the end of which Lac activity was depleted, and 37% of VP activity was left. Free enzymes, IL, IP, co-immobilized Lac, and VP were applied to biorefinery wastewater (BRW) in a batch study to investigate the transformation of phenolic contaminants over a period of 5 days. The major classes of phenolic constituents in terms of their order of removal in a Lac-VP system was phenol >2-chlorophenol > trichlorophenol > dichlorophenol > cresols > dimethylphenol >2 methyl- 4, 6-dinitrophenol > 4-nitrophenol > tetrachlorophenols > pentachlorophenol. The free enzymes and individually immobilized enzymes resulted in 80% dephenolization in 5 days. By contrast, the co-immobilized biocatalyst provided rapid dephenolization yielding the same 80% removal within 24 h and 96% removal of phenols in 60 h after which the system stabilized, which is the major advantage of the co-immobilized biocatalyst.

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Geographical analysis of tourism sites in Andaman Archipelago (India) and ecotourism development for Smith Island of North Andaman

This paper applies the nearest-neighbour analysis to analyse the clustering of tourist attractions in Andaman region and suggests ecotourism development for Smith Island of North Andaman using remote sensing techniques. The results indicated that present tourism sites are distributed in clusters in three regions (Port Blair, Mayabunder and Diglipur). To avoid concentration of tourism sites and population pressure in one particular area, there is a need to promote tourism to other locations as well. The study provided suggestions for ecotourism development in Smith Island after analysing its various ecological features to support the Andaman Administration’s vision to promote ecotourism.     

Thoron levels in the dwellings of Hyderabad city, Andhra Pradesh, India

Thoron and its progeny concentration levels were measured in the urban Hyderabad area using solid state nuclear track detector (SSNTD) based dosimeters. Measurements were carried out on quarterly cycles making four measurements at each location in a calendar year. More than 100 dwellings of different construction types were chosen for the study across Hyderabad city. The thoron concentration levels were found to vary between 8 and 330 Bq m(-3). The geometric mean value of thoron concentration was found to be 37.3 Bq m(-3) (GSD = 2.3) with an average of 55 +/- 57 Bq m(-3). Results were analysed for different category of houses with respect to their construction type. It was found that the dwellings with mud flooring had higher thoron levels.